I know that I can go into file properties and change the initial view to open the bookmark panel, but is there a way to make Acrobat default for all files?
LWILSON
AFAIK, no, you can't force that.
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You can set a default view that applies only to PDF files that do not specify a Navigation Panel view other then "Defualt".
You are very limited on forcing this view to all PDFs. It is possible to add a button that can open the bookmark panel.