There is no simple solution to this problem. Some printers allow you to add blank pages by defining "chapter pages" - but this requires the printer to support that.
You can however print a "section" based on the bookmarks in the document by right-clicking on the bookmark and then selecting to "Print section":

This is unfortunately not one or two clicks per document, it's two clicks per section.
There are some JavaScript solutions that are possible for some documents, but to create a solution that works for all documents, you would need a custom Acrobat plug-in.
Karl Heinz Kremer
PDF Acrobatics Without a Net
PDF Software Development, Training and More...
http://www.khkonsulting.com